Search results for " electrolysis"
showing 10 items of 27 documents
A stacked interleaved DC-DC buck converter for proton exchange membrane electrolyzer applications: Design and experimental validation
2019
Abstract Since the two last decades, hydrogen production has been attracting the attention of the scientific community thanks to its inherent very low pollution when energy coming from renewable energy sources (RESs) are used. However, it implies the use of DC/DC converters to interface source and load. These conversion systems must meet several requirements from current ripple point of view, energy efficiency, and performance to preserve the sustainability of hydrogen production. This article proposes the design and realization of a stacked interleaved buck converter to supply a proton exchange membrane electrolyzer. The converter is designed to ensure a low output current ripple and a sui…
Eulerian two-fluid model of alkaline water electrolysis for hydrogen production
2020
Hydrogen storage is a promising technology for storage of renewable energy resources. Despite its high energy density potential, the development of hydrogen storage has been impeded, mainly due to its significant cost. Although its cost is governed mainly by electrical energy expense, especially for hydrogen produced with alkaline water electrolysis, it is also driven by the value of the cell tension. The most common means of electrolyzer improvement is the use of an electrocatalyst, which reduces the energy required for electrochemical reaction to take place. Another efficient means of electrolyzer improvement is to use the Computational Fluid Dynamics (CFD)-assisted design that allows the…
Solvent Control in Electro-Organic Synthesis
2018
Exploiting the solvent control within electro-organic conversions is a far underestimated parameter in prep-scale electrolysis. The beneficial application in several transformations is outlined and in particular discussed for the dehydrogenative coupling of arenes and heteroarenes. This simple electrolytic strategy in fluorinated solvents allows the modulation of the substrate’s nucleophilicity and the stabilization of the intermediates as well as of the final product from over-oxidation.1 Introduction2 Solvent Effects in Kolbe Electrolysis and Anodic Fluorination3 Unique Solvent Effects of 1,1,1,3,3,3-Hexafluoropropan-2-ol (HFIP)4 Anodic Dehydrogenative Coupling Reactions with Use of HFIP …
Effect of coatings on long term behaviour of a commercial stainless steel for solid oxide electrolyser cell interconnect application in H2 /H2O atmos…
2014
Abstract K41X (AISI 441) stainless steel evidenced a high electrical conductivity after 3000 h ageing in H 2 /H 2 O side when used as interconnect for solid oxide electrolyser cells (SOEC) working at 800 °C. Perovskite (La 1 − x Sr x MnO 3 − δ ) and spinel (Co 3 O 4 ) oxides coatings were applied on the surface of the ferritic steel for ageing at 800 °C for 3000 h. Both coatings improved the behaviour of the steel and give interesting opportunities to use the K41X steel as interconnect for hydrogen production via high temperature steam electrolysis. Co 3 O 4 reduced into Co leading to a very good Area Specific Resistance (ASR) parameter, 0.038 Ω cm 2 . Despite a good ASR (0.06 Ω cm 2 ), La …
Dual atmosphere study of the K41X stainless steel for interconnect application in high temperature water vapour electrolysis
2015
Abstract High temperature water vapour electrolysis (HTE) is one of the most efficient technologies for mass hydrogen production. A major technical difficulty related to high temperature water vapour electrolysis is the development of interconnects working efficiently for a long period. Working temperature of 800 °C enables the use of metallic materials as interconnects. High temperature corrosion behaviour and electrical conductivity of a commercial stainless steel, K41X (AISI 441), were tested in HTE dual atmosphere (95%O 2 -5%H 2 0/10%H 2 -90%H 2 O) at 800 °C. The alloy exhibits a very good oxidation resistance compared to single atmosphere tests. However, a supplied electrical current s…
Design of a LLC Resonant Converter for Powering a PEM Electrolyzer
2021
International audience; This paper proposes the design of a LLC resonant converter to supply a proton exchange membrane (PEM) electrolyzer. The PEM requires a low voltage with high current, a reduced output voltage ripple, and an overdamped dynamic behavior of the converter to avoid voltage overshoots. The designed converter allows satisfying the design constraints, minimizing switching and reverse recovery losses; the efficiency is influenced mainly by the output rectifier's conduction losses.
Electrochemical incineration of 1,2-dichloroethane: Effect of the electrode material
2008
The electrochemical incineration of 1,2-dichloroethane (EDC) at Pt, Au, boron-doped diamond (BDD), Ebonex, stainless steel, Ti/IrO2–Ta2O5 and PbO2 has been studied in acid media by cyclic voltammetry and bulk electrolysis. It has been shown that the performances of the process dramatically depend on the anodic material. Higher current efficiencies were obtained at BDD. In particular, at proper values of applied current density, it is possible to obtain the almost complete conversion of EDC to CO2 at BDD with current efficiencies higher than 40%.
Hydrogen from The Sea: The Challenge of the Future. Present and Future Developments
2014
In this paper we proposed the use of saline water to product hydrogen. As far as using saline water, can be proposed two different scheme and technology. The aim of this work is to design an electrolyze system capable of utilizing sea water for direct electrolysis. It is probable that these systems would operate at a low power density and electrolyze only a small portion of the water in contact with electrodes. In particular, we present the results obtained by two different prototype of electrolyzer: one with steel electrodes and the second electrodes with titanium. Further experiments were carried out by changing the electrolytic solution of water and sodium chloride in real seawater. Fina…
Experimental Test and Simulations on a Linear Generator-Based Prototype of a Wave Energy Conversion System Designed with a Reliability-Oriented Appro…
2017
In this paper, we propose a reliability-oriented design of a linear generator-based prototype of a wave energy conversion (WEC), useful for the production of hydrogen in a sheltered water area like Mediterranean Sea. The hydrogen production has been confirmed by a lot of experimental testing and simulations. The system design is aimed to enhance the robustness and reliability and is based on an analysis of the main WEC failures reported in literature. The results of this analysis led to some improvements that are applied to a WEC system prototype for hydrogen production and storage. The proposed WEC system includes the electrical linear generator, the power conversion system, and a sea-wate…
Evolutionary Design Optimization of an Alkaline Water Electrolysis Cell for Hydrogen Production
2020
Hydrogen is an excellent energy source for long-term storage and free of greenhouse gases. However, its high production cost remains an obstacle to its advancement. The two main parameters contributing to the high cost include the cost of electricity and the cost of initial financial investment. It is possible to reduce the latter by the optimization of system design and operation conditions, allowing the reduction of the cell voltage. Because the CAPEX (initial cost divided by total hydrogen production of the electrolyzer) decreases according to current density but the OPEX (operating cost depending on the cell voltage) increases depending on the current density, there exists an optimal cu…